Product ID:4707-LIGHT GRAY CRU TILE-LIKE GLAZE COATING 08570
MSDS Date:12/13/1988
FSC:8010
NIIN:00F005620
MSDS Number: BKTCP

TENNANT COMPANY

701 NORTH LILAC DRIVE
MINNEAPOLIS, MN 55440

Emergency Phone: (612) 544-5163 OR (612) 738-9734

Info Phone: (612) 540-1381

Preparer: NORMAN W GILL

Cage: D0218

TENNANT COMPANY

1452 MINNEAPOLIS, MN 55440-1452 US

Telephone: 612-540-1556/800-553-8033

Cage: D0218

PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE,

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 40-50%

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-10%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,6-HEXAMETHYLENE DIISOCYANATE

CAS: 4035-89-6

RTECS: NR0195000

Fraction By Weight: 45-55%

LD50 LC50 Mixture:ORAL LD50 (RAT): 710,000 MG/CUM
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: BREATHING DIFFICULTY &
UPPER RESPIRATORY TRACT EFFECTS. SKIN: ABSORPTION & IRRITATION.
EYES: IRRITATION & INJURY. INGESTION: BURNING SENSATION, VOMITING,
DIARRHEA, DROWSINESS, TISSUE DAMAG E, CHEMICAL PNEUMONITIS, FATAL,
& KIDNEY & LIVER EFFECTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: BREATHING DIFFICULTY & UPPER
RESPIRATORY TRACT EFFECTS. SKIN: IRRITATION & ABSORPTION. EYES:
IRRITATION & INJURY. INGESTION: BURNING SENSATION, VOMITING,
DIARRHEA, DROWSINESS, TISSUE DAMAG E, CHEMICAL PNEUMONITIS, FATAL,
& KIDNEY & LIVER EFFECTS.

First Aid:SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/WATER FOR
15 MINS. INHALATIN: REMOVE TO FRESH AIR. RESTORE BREATHING IF
REQUIRED. INGESTION: DON'T INDUCE VOMITING. AVOID ASPIRATION INTO
THE LUNGS WHICH MAY CAUSE CHEMICAL PNEUMONITIS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.

Flash Point Method:SCC
Flash Point:108F
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:CLASS B EXTINGUISHERS SUCH AS CO2, DRY CHEMICAL, OR
FOAM
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE. WEAR SELF-CONTAINED
BREATHING APPARATUS. FOG NOZZLES ARE PREFERRED.
Unusual Fire/Explosion Hazard:USE WATER TO COOL CONTAINERS EXPOSED TO
EXTREME HEAT TO PREVENT PRESSURE BUILDUP, AUTOIGNITION, OR
EXPLOSION. COMBUSTIBLE LIQUID. DON'T APPLY TO HOT SURFACES.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE
AREA. REMOVE W/INERT ABSORBENT OR SCRUB W/SOAP & WATER.

Handling and Storage Precautions:STORE IN A COOL DRY PLACE. DON'T TAKE
INTERNALLY. AVOID CONTACT W/SKIN. AVOID FREE FALL OF LIQUID IN
EXCESS OF A FEW INCHES.
Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT,
ELECTRICAL EQUIPMENT, SPARKS, OPEN FLAMES, & HOT SURFACES. AVOID
INHALATION OF VAPORS.

Respiratory Protection:WEAR A CHEMICAL RESPIRATOR APPROVED FOR ORGANIC
VAPORS (NIOSH 23C OR EQUIVALENT) DURING THE APPLICATION & UNTIL THE
WORK AREA HAS BEEN EXHAUSTED OF ALL VAPORS.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP Protective Gloves:IMPERVIOUS SUCH AS RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
LD50 IS FOR 1,6-HEXAMETHYLENE DIISOCYANATE.

Boiling Pt:B.P. Text:295F
Vapor Pres:3.7
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN N-BU AC
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR LIQUID W/ESTER-LIKE ODOR.
Percent Volatiles by Volume:47%/WT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:IGNITION SOURCES SUCH AS EXTREME HEAT,
FLAMES, HOT SURFACES, ELECTRICAL, STATIC OR FRICTIONAL SPARKS
Hazardous Decomposition Products:CO2, CO, & NITROGEN OXIDES

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. COMBUSTIBLE LIQUID. NA 1993.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.